Mesoporous WO3-graphene photocatalyst for photocatalytic degradation of Methylene Blue dye under visible light illumination

Advanced oxidation technologies are a friendly environmental approach for the remediation of industrial wastewaters. Here, one pot synthesis of mesoporous WO_3 and WO_3-graphene oxide(GO) nanocomposites has been performed through the sol–gel method. Then, platinum(Pt) nanoparticles were deposited onto the WO_3 and WO_3-GO nanocomposite through photochemical reduction to produce mesoporous Pt/WO_3 and Pt/WO_3-GO nanocomposites. X-ray diffraction(XRD) findings exhibit a formation of monoclinic and triclinic WO_3 phases. Transmission Electron Microscope(TEM) images of Pt/WO_3-GO nanocomposites exhibited that WO_3 nanoparticles are obviously agglomerated and the particle sizes of Pt and WO_3 are ~ 10 nm and 20–50 nm, respectively. The mesoporous Pt/WO_3 and Pt/WO_3-GO nanocomposites were assessed for photocatalytic degradation of Methylene Blue(MB) as a probe molecule under visible light illumination.The findings showed that mesoporous Pt/WO_3, WO_3-GO and Pt/WO_3-GO nanocomposites exhibited much higher photocatalytic efficiencies than the pure WO_3. The photodegradation rates by mesoporous Pt/WO_3-GO nanocomposites are 3, 2 and 1.15 times greater than those by mesoporous WO_3, WO_3-GO, and Pt/WO_3, respectively. The key factors of the enhanced photocatalytic performance of Pt/WO_3-GO nanocomposites could be explained by the highly freedom electron transfer through the synergetic effect between WO_3 and GO sheets, in addition to the Pt nanoparticles that act as active sites for O2 reduction, which suppresses the electron hole pair recombination in the Pt/WO_3-GO nanocomposites.     

Bi-national assessment of the Great Lakes: SOLEC partnerships

Many administrative jurisdictions have authority over parts of the Great Lakes, sometimes with competing purposes as well as governance at differing scales of time and space. As demand increases for high quality information that is relevant to environmental managers, environmental and natural resource agencies with limited budgets must look to interdisciplinary, collaborative approaches for the collection, analysis and reporting of data. The State of the Lakes Ecosystem Conferences (SOLEC) were begun in 1994 in response to reporting requirements of the Great Lakes Water Quality Agreement between Canada and the U.S. The biennial conferences provide independent, science-based reporting on the state of health of the Great Lakes ecosystem components. A suite of indicators necessary and sufficient to assess Great Lakes ecosystem status was introduced in 1998, and assessments based on a subset of the indicators were presented in 2000. Because SOLEC is a multi-agency, multi-jurisdictional reporting venue, the SOLEC indicators require acceptance by a broad spectrum of stakeholders in the Great Lakes basin. The SOLEC indicators list is expected to provide the basis for government agencies and other organizations to collaborate more effectively and to allocate resources to data collection, evaluation and reporting on the state of the Great Lakes basin ecosystem.     

玄武湖蓝藻水华成因探讨

为了解南京玄武湖蓝藻水华的成因，对玄武湖长期监测资料进行了分析和现场调查。结果表明，玄武湖鲢鳙急剧减少中断了正常的食物链，使浮游植物的牧食压力降低，在东南湖回水的诱因作用下，发生了以微囊藻为优势种群的蓝藻水华。指出，玄武湖蓝藻水华的发生进程表明，东南湖回水可能是蓝藻水华发生的诱因，生态失衡是蓝藻水华发生的主要原因，蓝藻水华的暴发与富营养化程度无显著相关性，其暴发加重了玄武湖富营养化程度。     

混凝法在滇池蓝藻暴发期净水除藻的可行性研究

采用精制硫酸铝为混凝剂,L93^4正交法安排滇池蓝藻暴发期混凝沉降除藻除净水工艺实验。结果表明,混凝剂种类、水样pH值对蓝藻去除率有很大影响。研究确定了混凝剂除藻最佳操作条件,为混凝法去除蓝藻的工业化提供了理论和实际操作依据。     

固定化酵母菌对活性艳蓝KN-R的脱色研究

采用海藻酸钙加活性碳的方法对酵母菌进行固定化。正交试验结果表明，三者合适配比为海藻酸钠3％，活性碳10％，氯化钙4％。此方法制得的凝胶颗粒机械强度好、经久耐用。固定化酵母菌凝胶小球最适条件为：培养时间为48h，培养温度为37℃，培养基pH为3．0，凝胶量为10g。固定化细胞经多次脱色后能重复使用，4次脱色后其脱色率还达79．2％。     

MODELING HYDROLOGIC IMPACT OF WITHDRAWING THE GREAT LAKES WATER FOR AGRICULTURAL IRRIGATION1

ABSTRACT: Growing interest in agricultural irrigation in the Great Lakes basin presents an increasing competition to other uses of Great Lakes water. This paper, through a case study of the Mud Creek Irrigation District in the Saginaw Bay basin, Michigan, evaluates the potential hydrologic effects of withdrawing water for agricultural irrigation to the Great Lakes. Crop growth simulation models for corn, soybeans, dry beans, and the FAO Penman method were used to estimate the difference in evapotranspiration rates between irrigated and nonirrigated identical crops, based on climate, soil, and management data. The simulated results indicate that an additional 70–120 mm of water would be evapotranspirated during the growing season from irrigated crop fields as compared to nonirrigated identical plantings. Dependent upon the magnitude of irrigation expansion, an equivalent of about 1 to 5 mm of water from Lakes Huron-Michigan could be lost to the atmosphere. If agricultural irrigation further expands in the entire Great Lakes basin, the aggregated potential of water loss to the atmosphere through ET from all five Great Lakes would be even greater.     

Analysis of Lower Green Bay and Fox River,Collingwood Harbour,Spanish Harbour,and the Metro Toronto and Region remedial action plan (RAP) processes

This article presents a model of remedial action planning, which includes four key variables that determine progress in plan development and implementation and explain the differing level of achievement in individual sites. The model is illustrated by the characteristics and developments of four remedial action plan (RAP) processes (Lower Green Bay and Fox River, Collingwood Harbour, Spanish Harbour, and the Metro Toronto and Region RAPs). Differences in the local context of the plans have, to a significant degree, predisposed individual planning and implementation experiences. Local context includes three variables, namely geographical—technical and sociopolitical aspects and the previous history of water pollution management in the area. RAP precursors are a necessary precondition for progress in planning and substantive achievements. While there is a tendency that most geographically focused RAPs in administratively simple areas accomplish most, the motivation and political clout of RAP participants are strongly intervening factors. Resource input from upper levels of government, in particular financial commitment for plan implementation, is the fourth necessary ingredient for progress due to the RAPs' weak regulatory and institutional framework. Unfortunately, upper levels of government have shown widespread reluctance to lead in remedial action planning. This was only in part offset by local commitment and support for RAP and its cause.     

MODELING THE IMPACTS OF WATER LEVEL CHANGES ON A GREAT LAKES COMMUNITY1

ABSTRACT: Recent research that couples climate change scenarios based on general circulation models (GCM) with Great Lakes hydrologic models has indicated that average water levels are projected to decline in the future. This paper outlines a methodology to assess the potential impact of declining water levels on Great Lakes waterfront communities, using the Lake Huron shoreline at Goderich, Ontario, as an example. The methodology utilizes a geographic information system (GIS) to combine topographic and bathymetric datasets. A digital elevation surface is used to model projected shoreline change for 2050 using water level scenarios. An arbitrary scenario, based on a 1 m decline from February 2001 lake levels, is also modeled. By creating a series of shoreline scenarios, a range of impact and cost scenarios are generated for the Goderich Harbor and adjacent marinas. Additional harbor and marina dredging could cost as much as CDN $7.6 million. Lake freighters may experience a 30 percent loss in vessel capacity. The methodology is used to provide initial estimates of the potential impacts of climate change that can be readily updated as more robust climate change scenarios become available and is adaptable for use in other Great Lakes coastal communities.     

自然生态小区建设指导原则及其建设内容探讨--以筠连县大雪山自然生态小区为例

自然生态小区是构建优美生态环境区域的生态“细胞工程”。它根据当地的自然状况和社会经济状况,以较小的经济和社会代价实现一定区域生态环境优美、生态文明有序、生态系统良性循环的社会经济生态综合体。由于自然生态小区的建设是新兴事物,其建设途径还有很多问题值得探讨。在自然生态小区建设投资方面,应当明确生态环境建设投资和生产赢利建设投资,对于前者应当以政府和政策性投资为主,而后者应当是在政策法规规范下的企业投资为主;在发展模式方面,应当促进环境友好的规模化高效益产业,包括有机绿色产业、地方特色产业、民族文化产业等;在效益分配方面,必须要充分考虑整个社区居民资源共享和利益合理分配,实现整个社区生态文明建设和经济发展目标的一致。     

Containing spectacle in the transnational public sphere

ABSTRACT

This paper analyzes the discursive struggle over the reach and containment of spectacle in environmental politics to provide (a) case study-based evidence of how, on one hand, transnationally shared environmental awareness and concern, emerging in part through spectacle, is translating into expectations of participation and demands for accountability, and (b) how this is already impacting the ways in which environmental politics is being understood and enacted locally, regionally and transnationally. Drawing on recent mediated debate over the Great Barrier Reef, it finds that while the transnational is clearly an ambition for environmental campaigners, and the perception that transnational publics are emerging is already impacting environmental politics, the potency of these publics and their capacity to meaningfully negotiate accountability is yet to be empirically confirmed. Nevertheless, measures to contain spectacle are providing a potency for a transnational public sphere, even if in reality it is still little more than a specter.